Dichlorido(6-methyl-2,2′-bipyridine-κ2 N,N′)mercury(II)

نویسندگان

  • Roya Ahmadi
  • Amin Ebadi
  • Khadijeh Kalateh
  • Ali Norouzi
  • Vahid Amani
چکیده

In the mol-ecule of the title compound, [HgCl(2)(C(11)H(10)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a 6-methyl-2,2'-bipyridine ligand and two Cl atoms. There is a π-π contact between the pyridine rings [centroid-centroid distance = 3.9758 (5) Å].

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Dichlorido(6-methyl-2,2′-bipyridine-κ2 N,N′)cobalt(II)

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In the title compound, [ZnBr(2)(C(11)H(10)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a 6-methyl-2,2'-bipyridine ligand and two terminal Br atoms. Weak inter-molecular C-H⋯Br hydrogen bonds and π-π stacking inter-actions between the pyridine rings [centroid-centroid distances = 3.763 (5) and 3.835 (6) Å] contribute to crystal-packing...

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008